Diquat 敌草快

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敌草快

CAS No.:2764-72-9(阳离子);85-00-7(二溴盐)
英文名: diquat
化学名称:1,1'-乙撑-2,2'-联吡啶二溴盐
其他名称:催熟利;利农;杀草快;双快
分子式:C12H12N2Br2
分子量:344.05

理化性质:纯品为无色至淡黄色结晶,一水合物是淡黄色固体,熔点320℃(分解)。蒸气压<0.01MPa,密度d251.61g/cm3,在水中溶解度(20℃)为700g/L,微溶于乙醇和羰基溶剂,不溶于非极性有机溶剂.在酸性和中性溶液中稳定,但在碱性条件下不稳定.。

毒性: 中等毒性;大鼠急性经口LD50231mg/kg;小鼠急性经口LD50125mg/kg;兔经皮7400 mg/kg,对眼睛和对皮肤中等刺激性。。

作用特点及杀草谱: 敌草快是一种吡啶类广谱速效非选择性触杀型茎叶处理除草剂,比百草枯药效更快,对阔叶杂草效果更好。适用于非耕地、免耕地播前除草,果园、作物行间除草,也可用于大豆、棉花等作物收获前的催枯脱叶。用于作物催枯,用量为3~6g有效成分/100m2 。用于农田除草,夏玉米免耕除草用量为4.5~6g有效成分/100m2,果园为6~9有效成分/100m2。切忌对作物幼树进行直接喷雾,因接触作物绿色部分会产生药害。英国卜内门化学公司曾获准用利农20%水剂在我国进行小麦催枯试验。

剂型:20% W/V敌草快水剂(以阳离子含量计),15% W/V敌草快水剂(以二溴盐含量计)

生产方法:由吡啶在镍催化剂存在下氧化偶联,然后与1,2-二溴乙烷作用,环合成敌草快二溴盐。

生产情况:山东济南绿霸(800吨/年);南京红太阳集团有限公司(600吨/年);浙江永农化工有限公司。湖北潜江计划建设2000吨/年敌草快装置。

价格:敌草快原药(95%)价格15-16万元/吨(09.03);99.5%价格38万元/吨(09.08)

 

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diquat dibromide
Herbicide
HRAC D WSSA 22; bipyridylium

  diquat

NOMENCLATURE
diquat dibromide
IUPAC name 1,1'-ethylene-2,2'-bipyridyldiylium dibromide
Chemical Abstracts name 6,7-dihydrodipyrido[1,2-a:2',1'-c]pyrazinediium dibromide
CAS RN [85-00-7]; [6385-62-2] for diquat dibromide monohydrate EEC no. 201-579-4

diquat
Common name diquat (BSI, E-ISO, (m) F-ISO, ANSI, WSSA, JMAF); deiquat (Germany); reglon* (former exception, USSR)
IUPAC name 1,1'-ethylene-2,2'-bipyridyldiylium; 9,10-dihydro-8a,10a-diazoniaphenanthrene; 6,7-dihydrodipyrido-[1,2-a:2',1'-c]pyrazine-5,8-di-ium
Chemical Abstracts name 6,7-dihydrodipyrido[1,2-a:2',1'-c]pyrazinediium
CAS RN [2764-72-9] EEC no. 220-433-0

PHYSICAL CHEMISTRY
diquat dibromide
Mol. wt. 344.1 M.f. C12H12Br2N2 Form Colourless to yellow crystals. M.p. decomposes above 325 ºC (monohydrate) V.p. <0.01 mPa (monohydrate) KOW logP = -4.60 (20 ºC) Henry 5 ´ 10-9 Pa m3 mol-1 (calc.) S.g./density 1.61 (25 °C) Solubility In water 700 g/l (20 ºC). Slightly soluble in alcohols and hydroxylic solvents (25 g/l). Insoluble in non-polar organic solvents (<0.1 g/l). Stability Stable in neutral and acidic solutions, but readily hydrolysed in alkaline solutions. DT50 at pH 7 in simulated sunlight c. 74 d. Photochemically decomposed by u.v. irradiation, DT50 <1 w.

diquat
Mol. wt. 184.2 M.f. C12H12N2

COMMERCIALISATION
History Herbicide reported by R. C. Brian et al. (Nature (London), 1958, 181, 446). Introduced by ICI Plant Protection Division (now Syngenta AG) and first marketed in 1962. Patents GB 785732 Manufacturers Syngenta

APPLICATIONS
diquat dibromide
Biochemistry During photosynthesis, superoxide is generated, which damages cell membranes and cytoplasm. Mode of action Non-selective contact herbicide and desiccant, absorbed by the foliage, with some translocation in the xylem. Uses Pre-harvest desiccation of cotton, flax, alfalfa, clover, lupins, oilseed rape, poppies, soya beans, peas, beans, sunflowers, cereals, maize, rice, sugar beet, and other seed crops; destruction of potato haulms; and stripping of hops. Control of annual broad-leaved weeds in vines, pome fruit, stone fruit, bush fruit, strawberries (also control of runners), citrus fruit, olives, hops, vegetables, ornamental plants and shrubs, and other crops. Control of emergent and submerged aquatic weeds. Weed control on non-crop land. Weed control and tassel inhibition in sugar cane. Application rates 400-1000 g/ha. Formulation types SL; Gel. Compatibility Incompatible with alkaline materials, anionic surfactants (e.g. alkyl sulfonates or alkyl aryl sulfonates), and alkali-metal salts of hormone-type herbicides. Selected products: 'Reglone' (Syngenta); mixtures: 'Seccatuttu' (+ paraquat dichloride) (Syngenta)

OTHER PRODUCTS
diquat dibromide
'Boomerang' (GreenCrop); 'Desiquat' (Barclay); 'Midstream' (Scotts UK); 'Reglex' (Isagro) mixtures: 'PDQ' (+ paraquat dichloride) (Syngenta); 'Preeglox L' (+ paraquat dichloride) (Syngenta); 'Allzett' (+ glyphosate-trimesium) (Otsuka); 'Myzet' (+ paraquat dichloride) (Otsuka); 'Priglox' (+ paraquat dichloride) (Nihon Nohyaku); 'Speedway 2' (+ paraquat dichloride) (Scotts UK); 'Spray Seed' (+ paraquat dichloride) (Crop Care) Discontinued products: 'Midstream' * (Zeneca); 'Reglox' * (Zeneca); 'Aquacide' * (Nomix-Chipman) mixtures: 'Parable' * (+ paraquat dichloride) (Zeneca); 'Preglox' * (+ paraquat dichloride) (Zeneca)

ANALYSIS
Product analysis, and mixtures with paraquat, by u.v. spectrophotometry (AOAC Methods, 17th Ed., 969.08; CIPAC Handbook, 1992,E, 74). Free 2,2'-bipyridyl determined by glc (ibid., 1998, H, 153). Residues determined by colorimetry (M. G. Ashley, Pestic. Sci., 1970, 1, 101; A. Calderbank et al., Analyst (London), 1961, 86, 569; A. Calderbank & S. H. Yuen, ibid., 1965, 90, 95; 1966, 91, 625; J. E. Pack, Anal. Methods Pestic., Plant Growth Regul. Food Addit., 1967, 5, 397; J. B. Leary, Anal. Methods Pestic. Plant Growth Regul., 1978, 10, 321; Pestic. Anal. Man., 1979, II). Residues in potatoes by rplc with dual channel u.v. detection (AOAC Methods, 17th Ed., 992.17). Details available from Syngenta.

MAMMALIAN TOXICOLOGY
diquat dibromide
Reviews FAO/WHO 68, 70 (see part 2 of the Bibliography). Oral Acute oral LD50 for rats 408, mice 234 mg/kg. Skin and eye Acute percutaneous LD50 for rats >793 mg/kg. Irritating to skin and eyes (rabbits). Absorption through intact human skin is minimal; exposure can cause irritation and a delay in the healing of cuts and wounds. Can cause temporary damage to nails. Inhalation Extreme exposure to spray droplets may cause nose bleeding. NOEL (2 y) for rats 0.47 mg/kg b.w. daily; (4 y) for dogs 94 mg/kg diet. ADI (JMPR) 0.002 mg cation/kg b.w. [1993]; (EPA) 0.005 mg cation/kg b.w. [1995]. Water GV 10 mg cation/kg b.w. (provisional; based on ADI). Toxicity class WHO (a.i.) II (cation); EPA (formulation) II (a.i.) EC classification T+; R26| T; R48/25| Xn; R22| Xi; R36/37/38| R43| N; R50, R53

ECOTOXICOLOGY
diquat dibromide
Birds Acute oral LD50 for mallard ducks 155, partridges 295 mg/kg. Fish LC50 (96 h) for rainbow trout 39, mirror carp 125 mg/l. Daphnia LC50 (48 h) 2.2 mg/l. Algae EC50 (96 h) 21 mg/l. Bees LD50 (oral, 120 h) 22 mg/bee. Worms LC50 (14 d) 243 mg/kg.

ENVIRONMENTAL FATE
EHC 39 (WHO, 1984). Animals In rats, following oral administration of diquat dibromide, the dose is completely eliminated in the urine and faeces within 4 days. Plants Metabolic breakdown of diquat dibromide does not occur in plants. On plant surfaces, photochemical degradation occurs. Soil/Environment Rapidly degraded by soil micro-organisms, DT50 of unadsorbed diquat <1 w; strong binding in soil increases persistence. Strongly bound and inactivated by soil and aquatic sediments and does not leach into groundwater; Kd >10 000.