Cartap 杀螟丹

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杀螟丹

农药名称
中文名称 杀螟丹
英文名称 cartap
其他名称 巴丹、派丹 杀螟丹
毒性 杀螟丹属中等毒性杀虫剂。在正常条件下对眼睛和皮肤无过敏反应。未见致癌、致畸、致突变作用。对鱼有毒,对蜜蜂和家蚕有毒,对鸟类低毒,对蜘蛛等天敌无毒。 分子式:C7H15N3O2S2 ( · HCl)
性状:杀螟丹通常制成盐酸盐,外观白色晶体,有轻微奇臭味。183~183.5摄氏度分解,熔点(原药)179~181摄氏度。微溶于甲醇,难溶于乙醇,不溶于乙醚,丙酮,氯仿,苯等有机溶剂。在25摄氏度的水中溶解度为200g/L。在酸性介质中稳定,在碱性介质中部稳定,对铁等金属有腐蚀性。
毒性:雄性大鼠急性经口LD50为345MG/KG,雌性为325MG/KG,小鼠急性经口LD50192MG/KG。无致癌,制畸,致突变作用,对家蚕有毒,对鸟低毒,对蜘蛛等天敌安全。
剂型 50%可溶性粉剂。
特点 杀螟丹胃毒作用强,同时具有触杀和一定拒食、杀卵等作用。对害虫击倒快,残效期长,杀虫广谱。
开发 日本武田药品工业株式会社开发

适用范围
杀螟丹能用于防治鳞翅目、鞘翅目、半翅目、双翅目等多种害虫和线虫,对捕食性螨类影响较小。

使用方法
1、水稻害虫的防治 二化螟、三化螟每亩用50%可溶性粉75-100g,对水40-50kg喷雾。 稻纵卷叶螟、稻苞虫每亩用50%可溶性粉100-150g,对水50-60kg喷雾。
2、蔬菜害虫的防治 小菜蛾、菜青虫每亩用50%可溶性粉25-50g,对水50-60kg喷雾。
3、茶树害虫的防治 用50%可溶性粉1000-2000倍液均匀喷雾。
4、甘蔗害虫的防治 每亩用50%可溶性粉剂100-125g,对水50kg喷雾,或对水300kg淋浇蔗苗。
5、果树害虫的防治 用50%可溶性粉剂1000倍液均匀喷雾。
6、旱粮作物害虫的防治 玉米螟每亩用50%可溶性粉剂100g,对水100kg喷雾或均匀灌在玉米心内。蝼蛄用50%可溶性粉拌麦麸(1:50)制成毒饵施用。

注意事项
1、水稻杨花期或作物被雨露淋湿时不宜施药,喷药浓度高对水稻也会有药害,十字花科蔬菜幼苗对该药敏感,使用时小心。
2、若中毒,应立即洗胃,从速就医。

 

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cartap hydrochloride
Insecticide
IRAC 4C; 2-dimethylaminopropane-1,3-dithiol

  Cartap

NOMENCLATURE
cartap hydrochloride
Common name cartap hydrochloride
CAS RN [15263-52-2] cartap monohydrochloride; [22042-59-7] cartap, unspecified hydrochloride EEC no. 239-309-2

cartap
Common name cartap (BSI, E-ISO, (m) F-ISO, JMAF)
IUPAC name S,S'-(2-dimethylaminotrimethylene) bis(thiocarbamate)
Chemical Abstracts name S,S'-[2-(dimethylamino)-1,3-propanediyl] dicarbamothioate
CAS RN [15263-53-3] Development codes TI-1258 (Takeda)

PHYSICAL CHEMISTRY
cartap hydrochloride
Mol. wt. 273.8 M.f. C7H16ClN3O2S2 Form White crystalline, slightly hygroscopic solid with slight odour. M.p. 179-181 ºC (decomp.) V.p. Negligible Solubility In water c. 200 g/l (25 ºC). Very slightly soluble in methanol and ethanol. Insoluble in acetone, diethyl ether, ethyl acetate, chloroform, benzene, and hexane. Stability Stable in acidic conditions, but hydrolysed in neutral or alkaline media.

cartap
Mol. wt. 237.3 M.f. C7H15N3O2S2 Form White crystalline powder. M.p. 187-188 °C V.p. 2.5 ´ 10-2 mPa (25 °C) Solubility In hexane, toluene, chloroform, acetone and ethyl acetate <0.01, methanol 16.0 (all g/l, 20 °C). Stability Stable at 150 °C.

COMMERCIALISATION
History Insecticide reported by M. Sakai et al. (Jpn. J. Appl. Entomol. Zool., 1967, 11, 125), its action and structure-activity relationships reviewed (K. Konishi, Pestic. Chem. [Congr. Pestic. Chem., 2nd, 1971], 1972, 1, 179; M. Sakai & Y. Sato, ibid., p. 445; M. Sakai, Jpn. Pestic. Inf., 1971, No. 6, p. 15; 1978, No. 34, p. 22). The hydrochloride introduced by Takeda Chemical Industries, Ltd (now Sumitomo Chemical Takeda Agro Company Ltd) and first marketed in Japan in 1967. Patents GB 1126204; US 3332943; FR 1452338 Manufacturers Hunan Linxiang; Kuo Ching; Sharda; Sumitomo Chemical Takeda; Sundat

APPLICATIONS
Biochemistry Analogue or propesticide of the natural toxin nereistoxin. Nicotinergic acetylcholine blocker, causing paralysis by blocking cholinergic transmissions in the central nervous systems of insects. Mode of action Systemic insecticide with stomach and contact action. Insects discontinue feeding, and die of starvation.

cartap hydrochloride
Uses Cartap hydrochloride is used, at c. 0.4-1.0 kg/ha, for control of chewing and sucking insects (particularly Lepidoptera and Coleoptera), at almost all stages of development, on many crops, including rice (Chilo suppressalis, Cnaphalocrocis medinalis, Lissorhoptrus oryzophilus and rice-leaf beetle), potatoes, cabbage and other vegetables (Agromyzidae, Leptinotarsa decemlineata and Plutella xylostella); also on soya beans, peanuts, sunflowers, maize, sugar beet, wheat, pearl barley, pome fruit, stone fruit, citrus fruit, vines, chestnuts, ginger, tea, cotton, and sugar cane. Phytotoxicity May be phytotoxic to cotton, tobacco, and apples, under certain soil and climatic conditions. Formulation types DP; GR; SP. Compatibility Not compatible with pesticides which are alkaline. Selected products: 'Padan' (Sumitomo Chemical Takeda); 'Sanvex' (Sumitomo Chemical Takeda, Nagarjuna Agrichem); 'Hilcartap' (Hindustan); 'Mahadan' (Crop Health)

cartap
Selected products: 'Vicarp' (Vipesco)

OTHER PRODUCTS
cartap hydrochloride
'Cadan' (Sumitomo Chemical Takeda); 'Patap' (Sumitomo Chemical Takeda); 'Thiobel' (Sumitomo Chemical Takeda); 'Vegetox' (Sumitomo Chemical Takeda); 'Kritap' (Krishi Rasayan) mixtures: 'Dantotsupadan' (+ clothianidin) (Sumitomo Chemical Takeda); 'Dantotsupadanvalida' (+ clothianidin+ validamycin) (Sumitomo Chemical Takeda); 'Hustler' (+ clothianidin+ ferimzone+ phthalide+ validamycin) (Sumitomo Chemical Takeda)

cartap
'Caldan' (Sumitomo Chemical Takeda, Dhanuka); 'Pilartap' (Pilarquim) mixtures: 'Vipami' (+ isoprocarb) (Vipesco)

ANALYSIS
Product analysis by colorimetry on a derivative (CIPAC Handbook, 1988, D, 24). Residue analysis by glc or by polarography (K. Nishi et al., Anal. Methods Pestic. Plant Growth Regul., 1973, 7, 371).

MAMMALIAN TOXICOLOGY
Reviews FAO/WHO 74 (see part 2 of the Bibliography).

cartap hydrochloride
Oral Acute oral LD50 for male rats 345, female rats 325, male mice 150, female mice 154 mg/kg. Skin and eye Acute percutaneous LD50 for mice >1000 mg/kg; no irritation to skin or eyes in rabbits. Inhalation LC50 (6 h) for rats >0.54 mg/l. NOEL (2 y) for rats 10 mg/kg b.w. daily; (1.5 y) for mice 20 mg/kg b.w. daily. Toxicity class WHO (a.i.) II; EPA (formulation) II EC classification Xn; R21/22| N; R50, R53

cartap
ADI (JMPR) ADI withdrawn [1995].

ECOTOXICOLOGY
cartap hydrochloride
Fish LC50 for carp 1.6 mg/l (24 h) and 1.0 mg/l (48 h). Other aquatic spp. LC50 (24 h) for Moina macrocopa 12.5-25 mg/l. Bees Moderately toxic to honeybees.

ENVIRONMENTAL FATE
EHC 76 (WHO, 1988). Animals In rats, the carbonyl carbon is hydrolysed, and the sulfur oxidised, with N-demethylation of thiomethyl derivatives. No accumulation occurs in tissues. Rapidly excreted in the urine. Soil/Environment DT50 in soil c. 3 d.